Phenanthrylene-butadiynylene and Phenanthrylene-thienylene Macrocycles: Synthesis, Structure, and Properties

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Authors

PHULWALE Bhimrao Vaijnath MISHRA Sushil Kumar NEČAS Marek MAZAL Ctibor

Year of publication 2016
Type Article in Periodical
Magazine / Source Journal of Organic Chemistry
MU Faculty or unit

Faculty of Science

Citation
Web http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b00814
Doi http://dx.doi.org/10.1021/acs.joc.6b00814
Field Organic chemistry
Keywords SHAPE-PERSISTENT MACROCYCLES; ARYLENE-ETHYNYLENE MACROCYCLES; HYDROCARBON CHAIN-LENGTH; CONJUGATED MACROCYCLES; SPECTROSCOPIC PROPERTIES; PHOTOPHYSICAL PROPERTIES; ORGANIC MATERIALS; BUILDING-BLOCKS
Description A series of macrocycles consisting of 9,10-substituted phenanthrenes connected by butadiynylene linkers in positions 3 and 6 has been described as well as their transformation into the corresponding phenanthrylene-thienylene macrocycles. Structure and properties of the macrocycles, such as self-association in solution and optical and electrochemical properties, were studied and reported in a comparative manner with respect to the effects of the different sizes and shapes of the macrocycles and the character and length of their side chains.
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